21-4 N valve steel  |  21-12 N valve steel  |  X45CrSi93 valve steel  |  SUH3 / SUH11 Heat resisting steel bars
 
Typical Analysis :
Carbon 0.20% Manganese 1.75% Silicon 0.80%
Chromium 21.00% Nickel 11.50% Nitrogen 0.20%
 
Applications :
This alloy has been used as the head material in two-piece exhaust valves for both diesel and gasoline engines. It offers excellent high temperature strength and hardness as well as corrosion resistance to combustion products.
 
Workability :
Forging : 21-12 N can be readily forged by both upset and extrusion methods at temperatures in the range of 2050 / 2150 °F (1121 / 1177 °C). Do not forge at temperatures above 2200 °F (1204 °F) nor below 1800 °F (982 °C). Forgings can be rapidly cooled.
Machinability : Machinability properties are comparable to the standard 18-8 stainless alloys.
 
Heat Treatment :
Annealing : Heat approximately 1 hour at 1900 °F (1028 °C) and cool rapidly. This will result in a hardness of 241 BHN.
Stress Relieve Anneal : When required, parts can be stress relieved by holding at 1400 °F ( 760 °C) for 4 to 8 hours, followed by air cooling.
Solution Heat Treatment : For critical applications requiring maximum high temperature strength, forgings can be solution heat treatment at 2050 / 2150 °F (1121 / 1177 °C) and water quenched.
 
Typical Mechanical Properties :
Elevated Temperature Mechanical Properties
Specimens treated 1900 °F (1038 °C) water quenched
Test Temperature 0.2 % Yield Strength Ultimate Tensile Strength % Elongation In 4 D % Reduction Of Area Brinell Hardness V-Notch Charpy Impact
°F °C Ksi MPa Ksi MPa Ft-Ib J
77 25 75.0 17 123.5 852 42.0 60.0 241 74 100.0
1200 649 34.0 234 73.0 503 32.5 37.5 131 72 98.0
1350 732 29.5 203 52.2 360 33.0 53.0 120 70 95.1
1400 760 28.5 197 50.5 348 24.5 28.0 113 67 91.1
1500 816 27.0 186 40.5 279 22.0 30.0 72 73 99.0
 
Stress Rupture Properties at 1350 °F (732 °C)
Specimens treated 1900 °F (1038 °C), water quenched
  Time to Rupture
10 Hrs. 100 Hrs. 500 Hrs.
Stress to produce rupture,
psi (Mpa)% Elongation, 1'' (25.4 mm)
% Reduction of Area
29.000 (196) 18.000 (127) 13.000 (88)
26.0 27.0 41.0
35.0 28.0 40.0
 
 
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